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Charge transfer is a fundamental interface process that can be harnessed for light detection, photovoltaics, and photosynthesis. Recently, charge transfer was exploited in nanophotonics to alter plasmon polaritons by involving additional non-polaritonic materials to activate the charge transfer. Yet, direct charge transfer between polaritonic materials has not been demonstrated. We report the direct charge transfer in pure polaritonic van der Waals (vdW) heterostructures of α-MoO3/graphene. We extracted the Fermi energy of 0.6 eV for graphene by infrared nano-imaging of charge transfer hyperbolic polaritons in the vdW heterostructure. This unusually high Fermi energy is attributed to the charge transfer between graphene and α-MoO3. Moreover, we have observed charge transfer hyperbolic polaritons in multiple energy–momentum dispersion branches with a wavelength elongation of up to 150%. With the support from the density functional theory calculation, we find that the charge transfer between graphene and α-MoO3, absent in mechanically assembled vdW heterostructures, is attributed to the relatively pristine heterointerface preserved in the epitaxially grown vdW heterostructure. The direct charge transfer and charge transfer hyperbolic polaritons demonstrated in our work hold great promise for developing nano-optical circuits, computational devices, communication systems, and light and energy manipulation devices. 

We present Atacama Large Millimeter/sub-millimeter Array (ALMA) Cycle-5 observations of HBC 494, as well as calculations of the kinematic and dynamic variables which represent the object’s wide-angle bipolar outflows. HBC 494 is a binary FU Orionis type object located in the Orion A molecular cloud. We take advantage of combining the ALMA main array, Atacama Compact Array (ACA), and Total Power (TP) array in order to map HBC 494’s outflows and thus, estimate their kinematic parameters with higher accuracy in comparison to prior publications. We use 12CO, 13CO, C18O, and SO observations to describe the object’s outflows, envelope, and disc, as well as estimate the mass, momentum, and kinetic energy of the outflows. After correcting for optical opacity near systemic velocities, we estimate a mass of 3.0 × 10−2 M⊙ for the southern outflow and 2.8 × 10−2 M⊙ for northern outflow. We report the first detection of a secondary outflow cavity located approximately 15 arcsec north of the central binary system, which could be a remnant of a previous large-scale accretion outburst. Furthermore, we find CO spatial features in HBC 494’s outflows corresponding to position angles of ∼35° and ∼145°. This suggests that HBC 494’s outflows are most likely a composite of overlapping outflows from two different sources, i.e. HBC 494a and HBC 494b, the two objects in the binary system.

 

The internal velocity structure within dense gaseous cores plays a crucial role in providing the initial conditions for star formation in molecular clouds. However, the kinematic properties of dense gas at core scales (∼0.01−0.1 pc) has not been extensively characterized because of instrument limitations until the unique capabilities of GBT-Argus became available. The ongoing GBT-Argus Large Program, Dynamics in Star-forming Cores (DiSCo) thus aims to investigate the origin and distribution of angular momentum of star-forming cores. DiSCo will survey all starless cores and Class 0 protostellar cores in the Perseus molecular complex down to ∼0.01 pc scales with <0.05 km s−1 velocity resolution using the dense gas tracer N2H+. Here, we present the first data sets from DiSCo towards the B1 and NGC 1333 regions in Perseus. Our results suggest that a dense core’s internal velocity structure has little correlation with other core-scale properties, indicating these gas motions may be originated externally from cloud-scale turbulence. These first data sets also reaffirm the ability of GBT-Argus for studying dense core velocity structure and provided an empirical basis for future studies that address the angular momentum problem with a statistically broad sample.

 

Understanding the interplay between the inherent disorder and the correlated fluctuating-spin ground state is a key element in the search for quantum spin liquids. H₃LiIr₂O₆is considered to be a spin liquid that is proximate to the Kitaev-limit quantum spin liquid. Its ground state shows no magnetic order or spin freezing as expected for the spin liquid state. However, hydrogen zero-point motion and stacking faults are known to be present. The resulting bond disorder has been invoked to explain the existence of unexpected low-energy spin excitations, although data interpretation remains challenging. Here, we use resonant X-ray spectroscopies to map the collective excitations in H₃LiIr₂O₆and characterize its magnetic state. In the low-temperature correlated state, we reveal a broad bandwidth of magnetic excitations. The central energy and the high-energy tail of the continuum are consistent with expectations for dominant ferromagnetic Kitaev interactions between dynamically fluctuating spins. Furthermore, the absence of a momentum dependence to these excitations are consistent with disorder-induced broken translational invariance. Our low-energy data and the energy and width of the crystal field excitations support an interpretation of H₃LiIr₂O₆as a disordered topological spin liquid in close proximity to bond-disordered versions of the Kitaev quantum spin liquid.

 

For more than a century, Classical Nucleation Theory (CNT) has been used to explain the process of crystallization in supersaturated solutions. According to CNT, nucleation is a single-step process that occurs via monomer-by-monomer addition. However, recent findings from experiments and numerical simulations have shown that nucleation is a multi-step process that occurs via more complex pathways that involve intermediate species such as ion complexes, dense liquid precursors, or even nanocrystals. Such non-classical pathways observed in protein solutions, colloidal suspensions and electrolytes are reviewed in this paper. The formation of stable Pre-nucleation Clusters (PNCs) in the crystallization of biominerals is also discussed. In spite of the mounting evidence for non-classical nucleation behaviors, the knowledge about the structural evolution of the intermediate phases and their role in polymorph selection is still limited. It has also been observed that gravitational force interferes with the crystallization behavior of materials thereby posing limitation to ground-based experiments. Microgravity conditions, coupled with containerless processing techniques provide a suitable alternative to overcome these limitations. 

In this replication study, we examined gender differences in students’ math competence-related beliefs from 9th to 12th grade and tested gender differences within four racial/ethnic groups. In order to test the potential historical changes in these patterns and to counteract the replication crisis in psychology, this study employed six U.S. datasets collected from the 1980s to 2010s. Using a total sample of 24,290 students (49.5% male students; 11% African-, 9% Asian-; 30% Latinx- and 50% European-Americans), we found gender differences in students’ math competence-related beliefs favoring boys at all grade levels. By comparing effect sizes across datasets, we found no evidence that these gender differences varied by dataset or by historical time. The results across race/ethnicity with a subsample of 23,070 students indicated meaningful gender differences in students’ math competence-related beliefs favoring boys at all grade levels among Asian-, European-, and Latinx-Americans, but not among African-Americans where differences favored girls in 12th grade. Overall, our findings provide no evidence of historical changes concerning gender differences in students’ math competence-related beliefs across datasets. Our findings illustrate the importance of replicating empirical findings across datasets and using an intersectional lens to investigate math motivation.